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Journal Articles

A Proposed method to estimate in situ dissolved gas concentrations in gas-saturated groundwater

Tamamura, Shuji*; Miyakawa, Kazuya; Aramaki, Noritaka*; Igarashi, Toshifumi*; Kaneko, Katsuhiko*

Groundwater, 56(1), p.118 - 130, 2018/01

Groundwater saturated with gas forms bubble under atmospheric pressure, bothering most authorized methods to determine in-situ dissolved gas concentrations. To circumvent this problem, a simple theory to quantify effect of $rm bubble formation on in-situ dissolved gas concentration was developed: Pressure ({it P$_{i},rm original $}$ [bar]) of a gas component "${it i}$" (e.g., CH$$_{4}$$, CO$$_{2}$$ and H$$_{2}$$) in equilibrium with in-situ dissolved concentration (${it C $_{i},rm original $}$ [mol L $$^{-1}$$]) was related to partial pressure of the $rm bubble ({it P $_{i},rm bubble $}$ [bar]) emerged from groundwater in the form: ${it P$_{i},rm original $}$ = ${it P $_{i},rm bubble $}$ + $$Delta$$ ${it P}$ (k${it i}$' ${it P $_{i},rm bubble $}$/($$Sigma$$ ${it j}$k${it j}$' ${it P $_{ j },rm bubble $}$)), where $$Delta$$ ${it P}$ [bar] is groundwater pressure difference before and after the $rm bubble formation, and j refers to all gas components in the system including "{it i.}$" The k${it $_{i}$}$' and k${it $_{j}$}$' corresponds to the Henry's constant [bar L mol$$^{-1}$$] of ${it i}$ (k${it $_{i}$}$) and ${it j}$ (k${it $_{j}$}$), respectively, except for k$$_{CO2}$$', which is pH-dependent function. Dissolved CH$$_{4}$$ concentrations were successfully estimated by the model within the error of $$pm$$ 4.0% from the direct measurements by the sealed sampler method. Similar TIC concentration in the groundwater before and after the rm bubble formation was consistent with the model prediction. The wide application of the model is suggested without selecting sampling locations.

JAEA Reports

None

PNC TJ7439 93-003, 81 Pages, 1993/03

PNC-TJ7439-93-003.pdf:4.83MB

no abstracts in English

Oral presentation

Generation processes of methane and carbon dioxide at deep underground of Horonobe area, Hokkaido, Japan

Miyakawa, Kazuya; Mizuno, Takashi; Hirota, Akinari*; Komatsu, Daisuke*; Tsunogai, Urumu*

no journal, , 

no abstracts in English

Oral presentation

In-situ tracer migration tests for fractures in siliceous mudstone; Setting of test conditions under groundwater environment involving dissolved-gas

Takeda, Masaki; Ishii, Eiichi; Ono, Hirokazu; Kawate, Satoshi

no journal, , 

no abstracts in English

Oral presentation

Research on the effects of microbial methane oxidation on drill-core head-space gas analysis

Miyakawa, Kazuya; Okumura, Fumiaki*

no journal, , 

no abstracts in English

Oral presentation

Evaluation of pH changes associated with long-term geological processes; An Effect of degassing

Miyakawa, Kazuya; Sasamoto, Hiroshi; Murakami, Hiroaki

no journal, , 

no abstracts in English

Oral presentation

Development of simulation code of bubble and dissolved gas behavior in sodium-cooled fast reactor primary coolant system, 1; Study on analytical model for tank type reactor

Matsushita, Kentaro; Ito, Kei*; Ezure, Toshiki; Tanaka, Masaaki

no journal, , 

In a sodium-cooled fast reactor, from the viewpoint of prevention of core reactivity disturbance, it is important to evaluate the bubbles and dissolved gas behavior in the primary coolant system due to gas entrainment. For this reason, a numerical simulation code SYRENA for bubble and dissolved gas behavior analysis in the fast reactor primary coolant system has been developed in JAEA. In this study, a flow network model of SYRENA for tank type reactor was constructed and numerical simulations aiming to compare the bubble behavior characteristics in the loop type reactor and the tank type reactor was performed as a part of the fundamental validations of the flow network model of SYRENA. As the result, it was clarified that the differences regarding the bubbles and dissolved gas behavior between two different type reactors were indicated.

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